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Metalloheterocyclic compounds

Organic compounds that contain one or more heterocycles that contain one metallic element; heterocycles are rings that contain atoms from two or more types of elements.

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1

1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) tetrafluoroborate, 97%, Thermo Scientific Chemicals

CAS: 228121-39-9 Molecular Formula: C30H48BF4P2Rh Molecular Weight (g/mol): 660.37 MDL Number: MFCD01862464 InChI Key: DSYBEQKPSKLNMC-RTXTXWNLNA-N PubChem CID: 11549211 IUPAC Name: cyclooctane;(2R,5R)-1-[2-[(2R,5R)-2,5-diethylphospholan-1-yl]phenyl]-2,5-diethylphospholane;rhodium;tetrafluoroborate SMILES: [Rh+].F[B-](F)(F)F.C1C\C=C/CC\C=C/1.CC[C@@H]1CC[C@@H](CC)P1C1=C(C=CC=C1)P1[C@H](CC)CC[C@H]1CC

PubChem CID 11549211
CAS 228121-39-9
Molecular Weight (g/mol) 660.37
MDL Number MFCD01862464
SMILES [Rh+].F[B-](F)(F)F.C1C\C=C/CC\C=C/1.CC[C@@H]1CC[C@@H](CC)P1C1=C(C=CC=C1)P1[C@H](CC)CC[C@H]1CC
IUPAC Name cyclooctane;(2R,5R)-1-[2-[(2R,5R)-2,5-diethylphospholan-1-yl]phenyl]-2,5-diethylphospholane;rhodium;tetrafluoroborate
InChI Key DSYBEQKPSKLNMC-RTXTXWNLNA-N
Molecular Formula C30H48BF4P2Rh
2

1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I) tetrafluoroborate, 97%, Thermo Scientific Chemicals

CAS: 213343-65-8 Molecular Formula: C22H40BF4P2Rh Molecular Weight (g/mol): 556.22 MDL Number: MFCD09038435 InChI Key: CVUPEPGZCZHSOF-BDNLEJQTNA-N Synonym: 1,2-bis 2s,5s-2,5-dimethylphospholano ethane cyclooctadiene rhodium i tetrafluoroborate,--1,2-bis 2s,5s-2,5-dimethylphospholano ethane cyclooctadiene rhodium i tetrafluoroborate,s,s-me-bpe-rh,--1,2-bis 2s,5s-2,5-dimethylphospholano ethane cyclooctadiene-rhodium i tetrafluoroborate PubChem CID: 12964417 SMILES: [Rh+].F[B-](F)(F)F.C1C\C=C/CC\C=C/1.C[C@H]1CC[C@H](C)P1CCP1[C@@H](C)CC[C@@H]1C

PubChem CID 12964417
CAS 213343-65-8
Molecular Weight (g/mol) 556.22
MDL Number MFCD09038435
SMILES [Rh+].F[B-](F)(F)F.C1C\C=C/CC\C=C/1.C[C@H]1CC[C@H](C)P1CCP1[C@@H](C)CC[C@@H]1C
Synonym 1,2-bis 2s,5s-2,5-dimethylphospholano ethane cyclooctadiene rhodium i tetrafluoroborate,--1,2-bis 2s,5s-2,5-dimethylphospholano ethane cyclooctadiene rhodium i tetrafluoroborate,s,s-me-bpe-rh,--1,2-bis 2s,5s-2,5-dimethylphospholano ethane cyclooctadiene-rhodium i tetrafluoroborate
InChI Key CVUPEPGZCZHSOF-BDNLEJQTNA-N
Molecular Formula C22H40BF4P2Rh
3

9-Borabicyclo[3.3.1]nonane, 0.5M solution in THF, AcroSeal™

CAS: 280-64-8 | C8H15B | 122.02 g/mol

Molecular Weight (g/mol) 122.02
CAS Min % 92.49
Chemical Name or Material 9-Borabicyclo[3.3.1]nonane
SMILES [B]1C2CCCC1CCC2
InChI Key AMKGKYQBASDDJB-UHFFFAOYSA-N
Density 0.8840g/mL
PubChem CID 6327450
Fieser 02,31; 03,24; 04,41; 05,46; 06,62; 07,29; 08,47; 09,57; 10,48; 11,68; 13,92; 14,52; 15,43; 17,49; 01,732; 04,356
CAS 109-99-9
Health Hazard 3 GHS P Statement
Keep away from heat/sparks/open flames/hot surfaces.
- No smoking.
IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
Handle under inert gas.
Protect from moisture
MDL Number MFCD00074742
Health Hazard 2 GHS H Statement
In contact with water releases flammable gases.
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
May cause respiratory irritation.
Suspected of causing cancer.
May form explo
Solubility Information Solubility in water: reacts
Flash Point −17°C
Health Hazard 1 GHS Signal Word: Danger
Synonym 9-borabicyclo 3.3.1 nonane,9-borabicyclo 3.3.1 nonan,9-borabicyclo 3,3,1 nonane,9$l^ 2-borabicyclo 3.3.1 nonane,1s,5s-9-borabicyclo 3.3.1 nonane,monomer; 21205-91-4 dimer,9-borabicyclo 3.3.1 nonane,9-bbn,intetrahydrofuran
IUPAC Name 9$l^{2}-borabicyclo[3.3.1]nonane
Molecular Formula C8H15B
EINECS Number 206-000-9
Formula Weight 122.02
Specific Gravity 0.884
CAS Max % 93.86