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Nitrosonium tetrafluoroborate, 98%, Thermo Scientific Chemicals

Catalog Number p-7022854
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Quantity:
2 g
10 g
50 g
14635-75-7
BF4HNO2
133.82
MFCD00011433
XYRQURYIJKJVSF-UHFFFAOYSA-N
nitrosonium tetrafluoroborate, nitrosyl tetrafluoroborate, nitrosyltetrafluoroborate, nobf4, nitrilooxonium tetrafluoroborate, azanylidyneoxidanium tetrafluoroborate
11137142
azanylidyneoxidanium;tetrafluoroborate
[O-][NH+]=O.F[B-](F)(F)F
14635-75-7
BF4HNO2
133.82
MFCD00011433
XYRQURYIJKJVSF-UHFFFAOYSA-N
nitrosonium tetrafluoroborate, nitrosyl tetrafluoroborate, nitrosyltetrafluoroborate, nobf4, nitrilooxonium tetrafluoroborate, azanylidyneoxidanium tetrafluoroborate
11137142
azanylidyneoxidanium;tetrafluoroborate
[O-][NH+]=O.F[B-](F)(F)F

Nitrosonium tetrafluoroborate is a nitrosating agent and oxidizer used in organic synthesis. It is also used to convert arylamines directly to diazonium tetrafluoroborates, which undergo the Balz-Schiemann reaction in situ to give high yields of aryl fluorides. Further, it is used as a catalyst for iodination of aromatics by iodide ion with air as oxidant, conversion of secondary amines to nitrosamines and in deamination of primary amides. It is involved in the conversion of arylhydrazines to azides. In addition to this, it reacts with ferrocene to prepare ferrocenium tetrafluoroborate.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Nitrosonium tetrafluoroborate is a nitrosating agent and oxidizer used in organic synthesis. It is also used to convert arylamines directly to diazonium tetrafluoroborates, which undergo the Balz-Schiemann reaction in situ to give high yields of aryl fluorides. Further, it is used as a catalyst for iodination of aromatics by iodide ion with air as oxidant, conversion of secondary amines to nitrosamines and in deamination of primary amides. It is involved in the conversion of arylhydrazines to azides. In addition to this, it reacts with ferrocene to prepare ferrocenium tetrafluoroborate.

Solubility
Soluble in acetonitrile.

Notes
Hygroscopic. Air and moisture sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with acids and amines.
TRUSTED_SUSTAINABILITY
Boiling Point 250°C (0.01 mmHg)(Sublimation)
Melting Point 250°C (Sublimation)
Quantity 2 g
UN Number UN3260
Merck Index 14,6649
Solubility Information Soluble in acetonitrile.
Formula Weight 116.82
Percent Purity 98%
Odor Irritating
Sensitivity Moisture sensitive
Density 2.185
Chemical Name or Material Nitrosonium tetrafluoroborate
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RUO – Research Use Only

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