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  6. (1S,2R)-(-)-10,2-Camphorsultam, 99%

(1S,2R)-(-)-10,2-Camphorsultam, 99%

Product Code. 11422628
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Product Code. Quantity unitSize
11422628 5 g 5g
11412628 1 g 1g
11432628 25 g 25g
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Product Code. 11422628

Brand: Thermo Scientific Alfa Aesar A15897.06

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Description

CAS: 94594-90-8 | C10H17NO2S | 215.311 g/mol

(1S,2R)-(-)-10,2-Camphorsultam is used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine. It is used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones. It is also employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids. Also used to prepare N-acryloyl derivatives which are employed as dienophiles in asymmetric Diels-Alder reactions. and for other asymmetric transformations.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(1S,2R)-(-)-10,2-Camphorsultam is used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine. It is used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones. It is also employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids. Also used to prepare N-acryloyl derivatives which are employed as dienophiles in asymmetric Diels-Alder reactions. and for other asymmetric transformations.

Solubility
Slightly soluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong bases and strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 94594-90-8
Molecular Formula C10H17NO2S
Molecular Weight (g/mol) 215.311
MDL Number MFCD00066271
InChI Key DPJYJNYYDJOJNO-SZBHIRRCSA-N
Synonym 5r,7r-10,10-dimethyl-3??-thia-4-azatricyclo 5.2.1.0 1 ,? decane-3,3-dione, --10,2-camphorsultam;--exo-10,2-bornanesultam; 3as-3a, a,6, a,7a, a-hexahydro-8,8-dimethyl-3h-3a,6-methano-2,1-benzisothiazole-2,2-dioxide; 1s,5r-10,10-dimethyl-3-thia-4-azatricyclo 5.2.1.01,5 decane 3,3-dioxide
PubChem CID 54579826
SMILES CC1(C2CCC13CS(=O)(=O)NC3C2)C

Specifications

Melting Point 181°C to 186°C
Quantity 5 g
Beilstein 83811
Solubility Information Slightly soluble in water.
Optical Rotation −33° (c=1 in Ethanol)
Formula Weight 215.32
Percent Purity 99%
Chemical Name or Material (1S,2R)-(-)-10,2-Camphorsultam

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