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  8. Bis(triphenylphosphoranylidene)ammonium chloride, 97% (dry wt.), water <3%

Bis(triphenylphosphoranylidene)ammonium chloride, 97% (dry wt.), water <3%

Product Code. 11393476
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Quantity:
5 g
25 g
Unit Size:
25g
5g
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Product Code. 11393476

Brand: Thermo Scientific Alfa Aesar L14339.06

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Description

CAS: 21050-13-5 | C36H30ClNP2 | 574.04 g/mol

Co-catalyst used with a chiral Cobalt-salen complex for the asymmetric addition of carbon dioxide to propylene oxide. Also used in the preparation of 5-Hydroxy-clethodim Sulfoxide.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Co-catalyst used with a chiral Cobalt-salen complex for the asymmetric addition of carbon dioxide to propylene oxide. Also used in the preparation of 5-Hydroxy-clethodim Sulfoxide.

Solubility
Moderately soluble in water.

Notes
Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 21050-13-5
Molecular Formula C36H30ClNP2
Molecular Weight (g/mol) 574.04
MDL Number MFCD00151523
InChI Key LVRCYPYRKNAAMX-UHFFFAOYSA-M
Synonym 1,1,1-triphenyl-n-triphenylphosphoranylidene phosphoraniminium chloride, bis triphenylphosphoranylidene ammonium chloride, bis triphenylphosphoranylidene ammonium, triphenyl p,p,p-triphenylphosphine imidato-n phosphorus 1+ tetracarbonylcobaltate 1-, bis triphenylphosphine iminium chloride∼ppncl, ppn chloride, ppn cl, ksc491c1r, parent, triphenyl p,p,p-triphenylphosphine imidato phosphorus 1+ chloride
PubChem CID 3036656
IUPAC Name triphenyl-[(triphenyl-$l^{5}-phosphanylidene)amino]phosphanium;chloride
SMILES [Cl-].C1=CC=C(C=C1)P(=[N+]=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point 274°C to 276°C
Quantity 5 g
Beilstein 4097979
Solubility Information Moderately soluble in water.
Formula Weight 574.05
Percent Purity 97%
Assay (dry wt.), water <3%
Chemical Name or Material Bis(triphenylphosphoranylidene)ammonium chloride

Safety and Handling

compliance-icons
Product Identifier
  • Bis(triphenylphosphoranylidene)ammoniumchloride
 Signal Word
  • Warning
 Hazard Category
  • Serious eye damage/eye irritation Category 2
  • Skin corrosion/irritation Category 2
  • Specific target organ toxicity Category 3
 Hazard Statement
  • H315-Causes skin irritation.
  • H319-Causes serious eye irritation.
  • H335-May cause respiratory irritation.
 Precautionary Statement
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P312-Call a POISON CENTER/doctor/if you feel unwell.
  • P332+P313-If skin irritation occurs: Get medical advice/attention.
  • P337+P313-If eye irritation persists: Get medical advice/attention.
 Supplemental information
  • MIXTURE LIST-Contains : Bis(triphenylphosphoranylidene)ammoniumchloride
SDS

RUO – Research Use Only

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