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  7. Dibenzyl carbonate, 98%

Dibenzyl carbonate, 98%

Product Code. 11450343
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Product Code. 11450343

Brand: Thermo Scientific Alfa Aesar A11464.09

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Description

CAS: 3459-92-5 | C15H14O3 | 242.27 g/mol

Ionic liquids can effectively accelerate slow N-benzylation reactions utilizing dibenzyl carbonate as an alkylating reagent. Dibenzyl carbonate (DBzlC) has been used to benzylate phenylacetonitrile, benzyl phenylacetate and phenol. Selective N, N-dibenzylation of primary aliphatic amines was carried with dibenzyl carbonate in the presence of phosphonium salts.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Ionic liquids can effectively accelerate slow N-benzylation reactions utilizing dibenzyl carbonate as an alkylating reagent. Dibenzyl carbonate (DBzlC) has been used to benzylate phenylacetonitrile, benzyl phenylacetate and phenol. Selective N, N-dibenzylation of primary aliphatic amines was carried with dibenzyl carbonate in the presence of phosphonium salts.

Solubility
Sparingly Soluble (0.099 g/L) (25°C).

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, heat.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 3459-92-5
Molecular Formula C15H14O3
Molecular Weight (g/mol) 242.27
MDL Number MFCD00014436
InChI Key PIZLBWGMERQCOC-UHFFFAOYSA-N
Synonym carbonic acid, bis phenylmethyl ester, benzyl carbonate, carbonic acid, dibenzyl ester, dibenzylcarbonate, carbonic acid dibenzyl ester, phenylmethyl phenylmethoxy formate, dibenzyl carbonate, acmc-209i8r, carbonic acid,bis phenylmethyl ester
PubChem CID 77002
IUPAC Name dibenzyl carbonate
SMILES O=C(OCC1=CC=CC=C1)OCC1=CC=CC=C1

Specifications

Melting Point 27°C to 30°C
Boiling Point 150°C to 155°C (0.8 mmHg)
Flash Point >110°C (230°F)
Refractive Index 1.5485
Quantity 10 g
Beilstein 1882864
Sensitivity Air sensitive
Solubility Information Sparingly Soluble (0.099g/L) (25°C).
Formula Weight 242.27
Percent Purity 98%
Chemical Name or Material Dibenzyl carbonate
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