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Trichloroacetonitrile, 98%
Description
Trichloroacetonitrile is involved as a reagent in Overman rearrangement, which is used to prepare alylic amines from allylic alcohols. It is also used to prepare bistrichloroacetimidates from diols leading to dihyrooxazines through acid catalyzed cyclization. Further, it is utilized in the synthesis of trichloroacetimidates by 1,8-Diazobicyclo[5.4.0]undec-7-ene (DBU) catalyzed addition of allylic alcohols. It finds application in the study of the methoxy methyl (MOM) catalyzed aza-Claisen rearrangement.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Trichloroacetonitrile is involved as a reagent in Overman rearrangement, which is used to prepare alylic amines from allylic alcohols. It is also used to prepare bistrichloroacetimidates from diols leading to dihyrooxazines through acid catalyzed cyclization. Further, it is utilized in the synthesis of trichloroacetimidates by 1,8-Diazobicyclo[5.4.0]undec-7-ene (DBU) catalyzed addition of allylic alcohols. It finds application in the study of the methoxy methyl (MOM) catalyzed aza-Claisen rearrangement.
Solubility
Miscible with most organic solvents. Immiscible with water.
Notes
Incompatible with strong acids, strong bases, strong oxidizing agents and strong reducing agents.
Specifications
Specifica
| Melting Point | -44°C |
| Density | 1.44 |
| Boiling Point | 85°C to 86°C |
| Assay Percent Range | 98% |
| Linear Formula | Cl3CCN |
| Refractive Index | 1.441 |
| Quantity | 50 g |
| UN Number | UN3276 |
| Beilstein | 605572 |
| Merck Index | 14,9628 |
| Vedi altri risultati |
Sicurezza e movimentazione
- Trichloroacetonitrile
- Danger
- Acute toxicity Category 3
- LONG-TERM AQUATIC HAZARD Chronic 2
- H301-Toxic if swallowed.
- H311-Toxic in contact with skin.
- H331-Toxic if inhaled.
- H411-Toxic to aquatic life with long lasting effects.
- P273-Avoid release to the environment.
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
- P302+P352-IF ON SKIN: Wash with plenty of water/soap.
- P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P312-Call a POISON CENTER/doctor/if you feel unwell.
- MIXTURE LIST-Contains : Trichloroacetonitrile
RUO – Research Use Only
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