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  8. Triphenyl phosphite, 97%

Triphenyl phosphite, 97%

Product Code. 11462948
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Product Code. 11462948 Supplier Thermo Scientific Alfa Aesar Supplier No. A18662.36
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Description

CAS: 101-02-0 | C18H15O3P | 310.289 g/mol

Used to convert alcohols to alkyl halides, as a peptide coupling agent, and, in combination with ozone, as a low-temperature source of singlet oxygen, and ligand for metal-catalyzed reactions. Also used as reagent in the preparation of mixed valent nickel diphosphine dithiolate bridged iron carbonyl phosphine complexes as models of [NiFe]-hydrogenase active site.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Used to convert alcohols to alkyl halides, as a peptide coupling agent, and, in combination with ozone, as a low-temperature source of singlet oxygen, and ligand for metal-catalyzed reactions. Also used as reagent in the preparation of mixed valent nickel diphosphine dithiolate bridged iron carbonyl phosphine complexes as models of [NiFe]-hydrogenase active site.

Solubility
Insoluble in water.

Notes
Air and Moisture Sensitive, store away form air and moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under dry inert gas.
TRUSTED_SUSTAINABILITY

Identifiants chimiques

CAS 101-02-0
Molecular Formula C18H15O3P
Molecular Weight (g/mol) 310.289
MDL Number MFCD00003032
InChI Key HVLLSGMXQDNUAL-UHFFFAOYSA-N
Synonym phosphorous acid, triphenyl ester, advance tpp, triphenoxyphosphine, phenyl phosphite, stabilizer p 36, trifenoxyfosfin, trifenylfosfit, phosclere t 36, efed, mellite 310
PubChem CID 7540
IUPAC Name triphenyl phosphite
SMILES C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3

Spécification

Melting Point 22°C to 24°C
Density 1.184
Boiling Point 360°C
Flash Point 146°C (295°F)
Odor Mild
Linear Formula (C6H5O)3P
Quantity 500 g
UN Number UN3077
Sensitivity Air Sensitive
Solubility Information Insoluble in water.
Formula Weight 310.29
Percent Purity 97%
Chemical Name or Material Triphenyl phosphite
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Sécurité et traitement

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Identifiant produit
  • Triphenyl phosphite
 Mention d'avertissement
  • Warning
 Catégorie de danger
  • Acute toxicity Category 4
  • LONG-TERM AQUATIC HAZARD Chronic 1
  • ACUTE AQUATIC Acute 1
  • Serious eye damage/eye irritation Category 2
  • Skin corrosion/irritation Category 2
  • Skin sensitiser Category 1
 Mention de danger
  • H302-Harmful if swallowed.
  • H315-Causes skin irritation.
  • H317-May cause an allergic skin reaction.
  • H319-Causes serious eye irritation.
  • H400-Very toxic to aquatic life.
  • H410-Very toxic to aquatic life with long lasting effects.
 Conseils de prudence
  • P273-Avoid release to the environment.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
 Informations supplémentaires
  • MIXTURE LIST-Contains : Triphenyl phosphite
FDS

RUO – Research Use Only

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