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  7. Zirconium(IV) chloride, 98%, cont. 1-2% hafnium(IV) chloride, Thermo Scientific Chemicals

Zirconium(IV) chloride, 98%, cont. 1-2% hafnium(IV) chloride, Thermo Scientific Chemicals

Product Code. 11383716
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Product Code. 11383716 Supplier Thermo Scientific Alfa Aesar Supplier No. L14891.30
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Description

Zirconium(IV) chloride catalyzes the trans-hydrostannylation of acetylenes with Tri-n-butyl­tin hydride. It is used as a superior catalyst for the fries rearrangement of aryl acetates, giving the least hindered ortho-acetyl phenol in high yields at ambient temperatures. In the presence of ZrCl4, chloromethyl ethers are formed under mild conditions from acid chlorides and trioxane or paraformaldehyde.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Zirconium(IV) chloride catalyzes the trans-hydrostannylation of acetylenes with Tri-n-butyl­tin hydride. It is used as a superior catalyst for the fries rearrangement of aryl acetates, giving the least hindered ortho-acetyl phenol in high yields at ambient temperatures. In the presence of ZrCl4, chloromethyl ethers are formed under mild conditions from acid chlorides and trioxane or paraformaldehyde.

Solubility
Reacts with water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Handle and store under inert gas. It is sensitive to moisture. Incompatible with bases and oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 10026-11-6
Molecular Formula ZrCl4
MDL Number MFCD00011306
Synonym Zirconium tetrachloride

Specifications

Melting Point 331°C (sublimation)
Quantity 250 g
UN Number UN2503
Merck Index 14,10174
Solubility Information Reacts with water.
Formula Weight 233.03
Percent Purity 98%
Sensitivity Moisture sensitive
Density 2.803
Assay cont. 1 to 2% hafnium(IV) chloride
Chemical Name or Material Zirconium(IV) chloride
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