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4-Nitrobenzenesulfonyl chloride, 97%

Código de producto. 11438427
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Código de producto. 11438427 Proveedor Thermo Scientific Alfa Aesar N.º de proveedor A18512.36
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Descripción

CAS: 98-74-8 | C6H4ClNO4S | 221.61 g/mol

4-Nitrobenzenesulfonyl chloride is used as an intermediate for the synthesis of pharmaceuticals like foscmprenavir, darunavir and amprenavir. It is involved in the preparation of N-nosyl-alpha-amino acid for peptide synthesis. It is also used for stereoselective α-glucosylation of partially protected carbohydrates in association with silver tri-fluoromethanesulfonate, N,N-dimethylacetamide and triethylamine. It is widely used for the synthesis of hydroxylamines of sulfadiazine, sulfamethoxazole and [Cu(bipy)2Cl](nbs) (1) (bipy = 2,2'-bipyridine, nbs = 4-nitrobenzenesulfonate).

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
4-Nitrobenzenesulfonyl chloride is used as an intermediate for the synthesis of pharmaceuticals like foscmprenavir, darunavir and amprenavir. It is involved in the preparation of N-nosyl-alpha-amino acid for peptide synthesis. It is also used for stereoselective α-glucosylation of partially protected carbohydrates in association with silver tri-fluoromethanesulfonate, N,N-dimethylacetamide and triethylamine. It is widely used for the synthesis of hydroxylamines of sulfadiazine, sulfamethoxazole and [Cu(bipy)2Cl](nbs) (1) (bipy = 2,2′-bipyridine, nbs = 4-nitrobenzenesulfonate).

Solubility
Soluble in toluene, tetrahydrofuran, methylene chloride and ethyl acetate. Insoluble in water.

Notes
Moisture sensitive. Incompatible with strong oxidizing agents and strong bases.
TRUSTED_SUSTAINABILITY

Identificadores de productos químicos

CAS 98-74-8
Molecular Formula C6H4ClNO4S
Molecular Weight (g/mol) 221.61
MDL Number MFCD00007445
InChI Key JXRGUPLJCCDGKG-UHFFFAOYSA-N
Synonym 4-nitrobenzenesulfonylchloride, 4-nitrobenzene-1-sulfonyl chloride, benzenesulfonyl chloride, 4-nitro, 4-nitrobenzenesulphonyl chloride, 4-nitrophenylsulfonyl chloride, p-nitrophenylsulfonyl chloride, 4-nitrobenzenesulfonic acid chloride, p-nitrobenzenesulfonyl chloride, 4-nitrobenzenesulphonylchloride, 4-nitro-benzenesulfonyl chloride
PubChem CID 7404
SMILES [O-][N+](=O)C1=CC=C(C=C1)S(Cl)(=O)=O

Especificaciones

Melting Point 76°C to 80°C
Boiling Point 143°C to 144°C (1.5 mmHg)
Quantity 500 g
UN Number UN3261
Beilstein 746543
Sensitivity Moisture sensitive
Solubility Information Soluble in toluene,tetrahydrofuran,methylene chloride and ethyl acetate. Insoluble in water.
IUPAC Name 4-nitrobenzenesulfonyl chloride
Formula Weight 221.62
Percent Purity 97%
Chemical Name or Material 4-Nitrobenzenesulfonyl chloride
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