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Sodium ethoxide, 21% w/w in ethanol

Product Code. 11357876
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Product Code. 11357876 Supplier Thermo Scientific Alfa Aesar Supplier No. L13083.0F
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CAS: 141-52-6 | C2H5NaO | 68.051 g/mol

Sodium ethoxide, 21% w/w in ethanol is used as a strong base in organic synthesis. It finds application in various chemical reactions such as condensation, esterification, alkoxylation and etherifcation. It is actively involved in Claisen condensation, Stobbe reaction and Wolf-kishner reduction. It is an important starting material for the synthesis of ethyl ester and diethyl ester of malonic acid. In Williamson ether synthesis, it reacts with ethyl bromide to form diethyl ether.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Sodium ethoxide, 21% w/w in ethanol is used as a strong base in organic synthesis. It finds application in various chemical reactions such as condensation, esterification, alkoxylation and etherifcation. It is actively involved in Claisen condensation, Stobbe reaction and Wolf-kishner reduction. It is an important starting material for the synthesis of ethyl ester and diethyl ester of malonic acid. In Williamson ether synthesis, it reacts with ethyl bromide to form diethyl ether.

Solubility
Miscible with alcohol.

Notes
Moisture sensitive. It hydrolyzes rapidly into sodium hydroxide in the presence of moist air. Incompatible with water, strong bases, acids, oxidizing agents, alkali metals, strong oxidizing agents, ammonia, acid chlorides, acid anhydrides, reducing agents, peroxides, acids and chlorinated solvents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 141-52-6
Molecular Formula C2H5NaO
Molecular Weight (g/mol) 68.051
MDL Number MFCD00012417
InChI Key QDRKDTQENPPHOJ-UHFFFAOYSA-N
Synonym sodium ethoxide, sodium ethylate, sodium ethanolate, sodiumethoxide, ethoxysodium, ethanol, sodium salt, caustic alcohol, naoet, etona, ethanol, sodium salt 1:1
PubChem CID 2723922
ChEBI CHEBI:52096
IUPAC Name sodium;ethanolate
SMILES CC[O-].[Na+]

Specifications

Density 0.868
Flash Point 20°C (68°F)
Linear Formula NaOCH2CH3
Refractive Index 1.3875
Quantity 2500 mL
UN Number UN3274
Beilstein 3593646
Sensitivity Air and moisture sensitive
Merck Index 14,8613
Solubility Information Miscible with alcohol.
Formula Weight 68.05
Concentration or Composition (by Analyte or Components) 21% w/w in ethanol
Chemical Name or Material Sodium ethoxide
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For Manufacturing and Laboratory Use. Not for beverage use

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